122977-53-1Relevant academic research and scientific papers
A NEW METHOD FOR THE PREPARATION OF TERTIARY BUTYL ETHERS AND ESTERS
Armstrong, Alan,Brackenridge, Ian,Jackson, Richard F.W.,Kirk, Joanna M.
, p. 2483 - 2486 (1988)
T-butyl 2,2,2-trichloroacetimidate (1), readily prepared by addition of t-butanol to trichloroacetonitrile, is an efficient reagent for the preparation of t-butyl ethers and esters in the presence of a catalytic amount of boron trifluoride etherate.
Selective monoalkylation of acyclic diols by means of dibutyltin oxide and fluoride salts
Nagashima,Ohno
, p. 1972 - 1982 (2007/10/02)
Fluoride anion was found to promote monoalkylation reaction of diols by the stannylene acetal method, and selective monoalkylation of various acyclic diols was accomplished in good yields under mild conditions by employing this new method. Functional groups such as carboxylic acid ester, carboxamide, carbamate, nitrile, alkyl chloride, and ether were not affected under the reaction conditions.
