1229971-87-2Relevant articles and documents
Diversity-oriented synthesis of disubstituted alkenes using masked silanols
Sore, Hannah F.,Blackwell, David T.,MacDonald, Simon J. F.,Spring, David R.
, p. 2806 - 2809 (2010)
(Figure presented) The regio- and stereoselective synthesis and subsequent Hiyama cross coupling of pentafluorophenyldimethylvinylsilanes has been developed, thus providing a convenient and robust method for the diversity-oriented synthesis of (E)-, (Z)- and α-disubstituted alkenes from terminal alkynes. Pentafluorophenyldimethylvinylsilanes undergo cross-coupling reactions with excellent selectivity and in good yields, offering an attractive alternative to existing masked silanols.
