123044-80-4Relevant academic research and scientific papers
Iodomethyl group as a hydroxymethyl synthetic equivalent: Application to the syntheses of D-manno-hept-2-ulose and L-fructose derivatives
Bessières, Bernard,Morin, Christophe
, p. 4100 - 4103 (2007/10/03)
The one-carbon elongation of aldoses to ketoses using iodomethyllithium as the key reagent in the homologation step is exemplified by the preparation of two carbohydrates of chemical and biological interests: D-manno-hept-2-ulose from D-mannose and L-fructose from L-arabinose.
Highly Selective Synthesis of Aldonolactones from Protected Alditols by Ruthenium Complex-Catalyzed Dehydrogenation. A Method of Converting Aldopentoses to Their Strereoisomers
Saburi, Masahiko,Ishii, Youichi,Kaji, Nobutaro,Aoi, Tsuneo,Sasaki, Ichiro,et al.
, p. 563 - 566 (2007/10/02)
Highly selective hydrogen transfer reaction of substituted diols catalyzed by RuH2(PPh3)4 was applied to the conversion of aldopentoses into their stereoisomers via protected pentitols.Thus, the selective transformations of L-arabinose and L-ribose into p
