123060-66-2

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 123060-77-5 (E)-4-((1S,2R,3R,4R)-3-Benzyloxymethyl-1-hydroxy-5-oxo-bicyclo[2.2.2]oct-2-yl)-but-2-enoic acid methyl ester 
• 100-39-0 benzyl bromide 
• 123060-69-5 (1S,2R,3S,4R)-3-Hydroxymethyl-1-methoxymethoxy-5-oxo-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester 
• 123060-65-1 (1S,5R,6S,7R,8R)-6-Benzyloxymethyl-2-oxa-tricyclo[5.2.2.0^1,5]undecane-3,8-diol 
• 116205-36-8 (1S,2R,3S,4R)-3-Formyl-1-methoxymethoxy-5-oxo-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester 
• 123060-71-9 (1S,2R,3S,4R,5R)-3-Benzyloxymethyl-5-hydroxy-1-methoxymethoxy-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester 
• 123060-70-8 (1S,2R,3S,4R)-3-Benzyloxymethyl-1-methoxymethoxy-5-oxo-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester 
• 123060-72-0 (E)-4-((1S,2R,3S,4R,5R)-3-Benzyloxymethyl-1,5-dihydroxy-bicyclo[2.2.2]oct-2-yl)-but-2-enoic acid methyl ester 
• 123060-73-1 (1S,2R,3S,4R,5R)-3-Benzyloxymethyl-1-methoxymethoxy-5-(tetrahydro-pyran-2-yloxy)-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester 
• 123060-77-5 (E)-4-((1R,2S,3S,4S)-3-Benzyloxymethyl-1-hydroxy-5-oxo-bicyclo[2.2.2]oct-2-yl)-but-2-enoic acid methyl ester 
• 123122-96-3 (1R,2S,3R,4S)-3-Hydroxymethyl-1-methoxymethoxy-5-oxo-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester 
• 123060-65-1 (1R,5S,6R,7S,8S)-6-Benzyloxymethyl-2-oxa-tricyclo[5.2.2.0^1,5]undecane-3,8-diol 
• 116262-81-8 (1R,2S,3R,4S)-3-Formyl-1-methoxymethoxy-5-oxo-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester 

Downstream Products

• 123060-67-3 ((1R,2R,3aR,4R,5R,7aR)-4-Benzyloxymethyl-7a-methoxymethoxy-8-oxo-octahydro-1,5-methano-inden-2-yl)-acetic acid methyl ester 
• 123060-79-7 C₂₀H₂₄O₄ 
• 123060-68-4 C₂₀H₂₂O₄ 
• 123060-81-1 (R)-2-((1S,2S,3aR,4S,5R,7aR,8S)-4-Benzyloxymethyl-7a-hydroxy-8-methoxymethoxy-octahydro-1,5-methano-inden-2-yl)-propionaldehyde 
• 111596-68-0 (1R,5R,6S)-5-((S)-4-Benzyloxy-1-methyl-butyl)-10-methoxymethoxy-bicyclo[4.3.1]dec-2-en-7-one 
• 123060-80-0 C₂₂H₂₈O₅ 
• 123060-83-3 C₂₃H₃₀O₅ 
• 123060-82-2 (E)-(S)-4-((1S,2R,3aR,4S,5R,7aR,8S)-4-Benzyloxymethyl-7a-hydroxy-8-methoxymethoxy-octahydro-1,5-methano-inden-2-yl)-pent-2-enoic acid methyl ester 
• 123060-67-3 ((1S,2S,3aS,4S,5S,7aS)-4-Benzyloxymethyl-7a-methoxymethoxy-8-oxo-octahydro-1,5-methano-inden-2-yl)-acetic acid methyl ester 
• 123060-79-7 C₂₀H₂₄O₄ 
• 123060-68-4 C₂₀H₂₂O₄ 
• 123060-81-1 (S)-2-((1R,2R,3aS,4R,5S,7aS,8R)-4-Benzyloxymethyl-7a-hydroxy-8-methoxymethoxy-octahydro-1,5-methano-inden-2-yl)-propionaldehyde 
• 111596-68-0 (1S,5S,6R)-5-((R)-4-Benzyloxy-1-methyl-butyl)-10-methoxymethoxy-bicyclo[4.3.1]dec-2-en-7-one 
• 123060-80-0 C₂₂H₂₈O₅ 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF (-)- AND (+)-SANADAOL: THE ABSOLUTE CONFIGURATION OF SANADAOL AND DICTYODIAL

Both (-)- and (+)-sanadaol were synthesized stereoselectively from D-mannitol via chiral bicyclooctane derivative 4.This accomplishment determined the absolute configuration of sanadaol and that of dictyodial as shown by 1 and 3, respectively.