123075-95-6Relevant academic research and scientific papers
Homochiral Matching in the Diels-Alder Cyclodimerization of 2-Vinyl-7-oxabicyclohept-2-ene Derivatives.
Meerpoel, Lieven,Vrahami, Maria-Miranda,Ancerewicz, Jacek,Vogel, Pierre
, p. 111 - 114 (1994)
Keywords: Face selectivity, -cycloadditions, chiral recognition, (1R,2S,3S,4R,7R,11S,12R)-11-ethenyl-15,16-dioxapentacyclo4,7.03,8.02,11>hexadec-8-en-6,13-dione, (1R,2R,3R,4R,7R,11R,12R)-11-ethenyl-15,16-dioxapentacyclo4,7.03,8.02,11>hexadec-8-en-5,14-dione and their ethylene acetals.Abstract: Racemic 6-vinyl-7-oxabicyclohept-5-en-2-one, 5-vinyl-7-oxabicyclohept-5-en-2-one and their ethylene acetals undergo highly stereoselective Diels-Alder cyclodimerizations.The optically pure semicyclic dienes give the corresponding optically pure dimers with the same ease.
