Homochiral Matching in the Diels-Alder Cyclodimerization of 2-Vinyl-7-oxabicyclohept-2-ene Derivatives.

DOI: 10.1016/0040-4039(94)88176-6

Source and publish data:

Tetrahedron Letters p. 111 - 114 (1994)

Update date:2022-08-02

Topics:

Authors:

Meerpoel, Lieven

Vrahami, Maria-Miranda

Ancerewicz, Jacek

Vogel, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)88176-6

Keywords: Face selectivity, <4+2>-cycloadditions, chiral recognition, (1R,2S,3S,4R,7R,11S,12R)-11-ethenyl-15,16-dioxapentacyclo<10.2.1.1.^4,7.0^3,8.0^2,11>hexadec-8-en-6,13-dione, (1R,2R,3R,4R,7R,11R,12R)-11-ethenyl-15,16-dioxapentacyclo<10.2.1.1.^4,7.0^3,8.0^2,11>hexadec-8-en-5,14-dione and their ethylene acetals.Abstract: Racemic 6-vinyl-7-oxabicyclo<2.2.1>hept-5-en-2-one, 5-vinyl-7-oxabicyclo<2.2.1>hept-5-en-2-one and their ethylene acetals undergo highly stereoselective Diels-Alder cyclodimerizations.The optically pure semicyclic dienes give the corresponding optically pure dimers with the same ease.

Full text of DOI:10.1016/0040-4039(94)88176-6

Products guided by the article

Product name:2-endo-acetoxy-6-exo-(phenylselenenyl)-5-endo-bromo-7-oxabicyclo<2.2.1>heptane-2-exo-carbonitrile

Cas No:123075-95-6

R&D Labs maybe for 123075-95-6

ZK Biochem Group Co., Ltd

Contact:+86-532-80762375

Address:No. 6, Hongkong Middle Road, Qingdao, China
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Shandong Xinhua Pharmaceutical Co.,Ltd

website:http://www.xhzy.com

Contact:+86-533-2196801

Address:1 lutai road,zhangdian dis,Zibo City
Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA

Relevant to this article

'Click chemistry' synthesis of a library of 1,2,3-triazole-substituted galactose derivatives and their evaluation against Trypanosoma cruzi and its cell surface trans-sialidase

Doi:10.1016/j.bmc.2010.02.053
(2010)
Synthesis and evaluation of novel 1,3,4-thiadiazole–fluoroquinolone hybrids as antibacterial, antituberculosis, and anticancer agents

Doi:10.3906/kim-1710-35
(2018)
Amino-borane oligomers bound to a Rh(I) metal fragment

Doi:10.1039/c003055d
(2010)
Synthesis of β-Enaminophosphonates and β-Methoxyiminophosphonates

Doi:10.1134/S1070363209120263
(2009)
Synthesis of 2,4-disubstituted pyrimidin-5-yl C-2′- deoxyribonucleosides by sequential regioselective reactions of 2,4-dichloropyrimidine nucleosides

Doi:10.1002/ejoc.201000164
(2010)
Synthesis and hypolipidemic activity of novel 2-(4-(2-substituted aminothiazole-4-yl) phenoxy) acetic acid derivatives

Doi:10.1016/j.ejmech.2010.03.043
(2010)

Article Doi