1231204-93-5Relevant articles and documents
Rhenium carbyne and η2-vinyl complexes from one-pot reactions of ReH5(PMe2Ph)3 with terminal alkynes
Chen, Jiangxi,He, Guomei,Sung, Herman Ho-Yung,Williams, Ian Duncan,Lin, Zhenyang,Jia, Guochen
, p. 2693 - 2701 (2010)
Treatment of the rhenium polyhydride complex ReH5(PMe 2Ph)3 with HC≡CR (R = Ph, SiMe3, (CH 2)4Me) in the presence of 2.2 equiv of HCl produces a mixture of the carbyne complexes Re(≡CCH2R)Cl 2(PMe2Ph)3 and the η2-vinyl complexes Re(η2-CH2CR)Cl2(PMe 2Ph)3. When HC≡CC(OH)Ph2 was used, the reaction gave the carbyne complexes Re(≡CCH=CPh2)Cl 2(PMe2Ph)3 and Re(≡CCH 2C(OH)Ph2)Cl2(PMe2Ph)3 along with the η2-vinyl complex Re(η2-CH 2CC(OH)Ph2)Cl2(PMe2Ph)3.