123123-47-7

Basic information

• Product Name: (R)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-oxirane
• Synonyms: (R)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-oxirane
• CAS NO: 123123-47-7
• Molecular Weight: 326.511
• Mol File: 123123-47-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-oxirane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-oxirane(123123-47-7)
• EPA Substance Registry System: (R)-2-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-oxirane(123123-47-7)

Safety Data

• Hazardous Substances Data: 123123-47-7(Hazardous Substances Data)

Upstream product

• 86884-90-4 (S)-2-methylglycidol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 183957-65-5 (R)-1-azido-3-(tert-butyl-diphenyl-silanyloxy)-2-methyl-propan-2-ol 
• 183957-38-2 (S)-N-[1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-2-phenyl-ethyl]-4-methyl-benzenesulfonamide 
• 183957-66-6 (S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-2-methyl-1-(toluene-4-sulfonyl)-aziridine 
• 953786-78-2 C₅₄H₈₈SO₄Si₃ 
• 123067-89-0 (2R,4E-Z,5E,9E)-1-(tert-butyl-diphenyl-silanyloxy)-2,6,10,14-tetramethyl-4-toluenesulfonyl-pentadeca-5,9,13-trien-2-ol 

Relevant articles and documents

Asymmetric total synthesis of naturally occurring spirocyclic tetranorsesquiterpenoid lanceolactone A

Asymmetric total synthesis of naturally occurring γ-butenolide containing [4.4]spiro-tetrahydrofuran lanceolactone A has been reported in the present work. Bimetallic ("Pd-Cu") cascade cyclization was the crucial reaction employed for the construction of the γ-butenolide framework of the natural product. Subsequently, iodocyclization and reductive deiodination through a transfer hydrogenation reaction were applied to access the target molecule in an efficient manner.

Model studies directed toward forskolin: Synthesis of a tricyclic model compound from farnesol

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