123133-04-0Relevant articles and documents
Synthesis and Absolute Configuration of Optically Active Selenoxides. X-Ray Molecular Structure of (-)Se-4-Menthyloxycarbonylphenyl 2,4,6-Tri-isopropylphenyl Selenoxide
Shimizu, Toshio,Kikuchi, Koichi,Ishikawa, Yoshimitsu,Ikemoto, Isao,Kobayashi, Michio,Kamigata, Nobumasa
, p. 597 - 602 (2007/10/02)
Enantiomerically pure, stable 4-(methoxycarbonyl)phenyl 2,4,6-tri-isopropylphenyl selenoxide (-)-3 was isolated by fractional recrystallization of diastereomeric 4-phenyl 2,4,6-tri-isopropylphenyl selenoxide dia.-(1) followed by removal of the chiral source.The absolute configuration around the selenium atom was determined by X-ray crystallographic analysis of diastereomerically pure selenoxide (-)Se-(1).