1232394-75-0

Basic information

• Product Name: C₁₃H₁₃NO₃Si
• Synonyms: C₁₃H₁₃NO₃Si
• CAS NO: 1232394-75-0
• Molecular Weight: 259.337
• Mol File: 1232394-75-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₃NO₃Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₃NO₃Si(1232394-75-0)
• EPA Substance Registry System: C₁₃H₁₃NO₃Si(1232394-75-0)

Safety Data

• Hazardous Substances Data: 1232394-75-0(Hazardous Substances Data)

Upstream product

• 694-53-1 phenylsilane 
• 555-16-8 4-nitrobenzaldehdye 

Downstream Products

• 619-73-8 4-nitrobenzyl chloride 

Relevant articles and documents

Efficient Solvent-Free Hydrosilylation of Aldehydes and Ketones Catalyzed by Fe2(CO)9/C6H4-o-(NCH2PPh2)2BH

An efficient solvent-free catalyst system for hydrosilylation of aldehydes and ketones was developed based on iron pre-catalyst Fe2(CO)9/C6H4-o-(NCH2PPh2)2BH. The reactions were tolerant of many functional groups and the corresponding alcohols were isolated in good to excellent yields following basic hydrolysis of the reaction products. The reaction is likely catalyzed by an in situ generated pincer ligated iron hydride complex. Graphic Abstract: [Figure not available: see fulltext.]

Formation of Zn-Zn and Zn-Pd Bonded Complexes by Reactions of Terminal Zinc Hydrides with Pd(II) Species

Divalent palladium-induced homocoupling of terminal zinc hydrides to zinc-zinc bonded complexes was achieved herein. Reactions of zinc hydrides [LZnH] (L = CH3C(2,6-iPr2C6H3N)CHC(CH3)(N(CH2)nCH2PPh2); 1a: n = 1; 1b: n = 2) with 0.5 equiv of allyl(cyclopentadienyl)palladium(II) afforded heterotrinuclear [Zn2Pd] complexes 3 containing direct Zn-Zn and Zn-Pd bonds, with concomitant elimination of propylene and cyclopentadiene. Complexes 3 were also accessed by the reactions of zinc hydrides 1 with allylpalladium(II) chloride with release of propylene and hydrogen chloride. Treatment of zinc hydrides 1 with 1 equiv of allyl(cyclopentadienyl)palladium(II) gave Zn-Pd bonded complex 5 by elimination of propylene, which can be transformed into heterotrinuclear complex 3 by further reaction with one additional molar equivalent of zinc hydrides. Heterobimetallic Zn-Pd complex 5b was found to be an effective catalyst in the hydrosilylation of benzaldehyde and its derivatives. Reaction of 5b with silane reagent Ph2SiH2 produced [Pd2Si2H2] complex 8 with cleavage of the Pd-Zn bond, which served as an initiating species in the catalytic reaction. Complexes 4b, 5, and 8 in this study were characterized by X-ray diffraction.