123284-16-2

Upstream product

• 123187-28-0 (-)-(1S,6R)-4α-methoxy-3-(trimethylstannyl)-2-norcarene 
• 822-87-7 2-Chlorocyclohexanone 
• 123187-23-5 (+)-(1S,6R)-4α-methoxy-3-<<(trifluoromethyl)sulfonyl>oxy>-2-nor-carene 
• 4017-83-8 (-)-(1R,3R,6S)-4-methylene-7,7-dimethylbicyclo[4.1.0]heptan-3-ol 
• 123187-22-4 (+)-(1S,6R)-4α-methoxy-3-norcaranone 

Downstream Products

• 123284-19-5 (1R,2S)-2-((1S,4R,6R)-4-Methoxy-7,7-dimethyl-bicyclo[4.1.0]hept-2-en-3-yl)-1-vinyl-cyclohexanol 
• 123284-18-4 (1S,2S)-2-((1S,4R,6R)-4-Methoxy-7,7-dimethyl-bicyclo[4.1.0]hept-2-en-3-yl)-1-vinyl-cyclohexanol 

Relevant academic research and scientific papers

Tandem anionic [3,3] sigmatropy and SN′ displacement. New synthetic technology for the construction of hydroazulenone and related frameworks

Transmetalation of the 3-(trimethylstannyl)-2-norcarenes 9 and 28b provides for the acquisition of optically pure bicyclic vinyllithium derivatives. These have been added to (±)-2-chlorocyclohexanone and the resultant cis-chlorohydrins have been exposed t

Stereocontrolled Construction of Hydroazulenones by Sequential Anionic Oxy-Cope Rearrangement-SN' Allylic Ether Displacement

The possibility of generating hydroazulenone frameworks in stereocontrolled fashion is demonstrated with a 4α-methoxy-2-norcaren-3-yl example.This optically pure system illustrates in an especially revealing way the stereochemical issues surrounding assembly of the ketonic products.