123299-34-3Relevant articles and documents
ISOCAMPHANONE IN SYNTHESIS OF 3-ALKYL- AND 6-ALKYL-SUBSTITUTED CAMPHOR DERIVATIVES
Kozlov, N. G.,Popova, L. A.,Vyalimyae, T. K.,Nesterov, G. V.,Knizhnikov, V. O.,Ol'dekop, Yu. K.
, p. 686 - 690 (1988)
On the interaction of isocamphanone with butyllithium, 2-butyl-5,5,6-trimethylbicycloheptan-endo-2-ol is formed stereospecifically.As a result of skeletal rearrangements of carbonium ions taking place in the course of the reaction, the Ritter reaction of this tertiary alcohol with acetonitrile and benzonitrile has given endo-3-butyl-1,7 7-trimethylbicyclohept-exo-2-ylacylamines and endo-6-butyl-1,7,7-trimethylbicyclohept-2-ylacylamines.