Chemistry of Natural Compounds p. 686 - 690 (1988)
Update date:2022-08-03
Topics:
Kozlov, N. G.
Popova, L. A.
Vyalimyae, T. K.
Nesterov, G. V.
Knizhnikov, V. O.
Ol'dekop, Yu. K.
On the interaction of isocamphanone with butyllithium, 2-butyl-5,5,6-trimethylbicyclo<2.2.1>heptan-endo-2-ol is formed stereospecifically.As a result of skeletal rearrangements of carbonium ions taking place in the course of the reaction, the Ritter reaction of this tertiary alcohol with acetonitrile and benzonitrile has given endo-3-butyl-1,7 7-trimethylbicyclo<2.2.1>hept-exo-2-ylacylamines and endo-6-butyl-1,7,7-trimethylbicyclo<2.2.1>hept-2-ylacylamines.
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