123330-49-4Relevant academic research and scientific papers
Photochemistry of Fluorinated Aryl Azides in Toluene Solution and in Frozen Polycrystals
Leyva, Elisa,Munoz, Daniel,Platz, Matthew S.
, p. 5938 - 5945 (1989)
Several fluorinated triplet aryl nitrenes have been generated in low-temperature polycrystals by photolysis of the corresponding azides.Upon extended photolysis at -196 deg C the nitrenes abstract hydrogen from frozen toluene to give anilino-benzyl radical pairs, which subsequently combine to give CH insertion products.The radical pairs and the triplet nitrenes have been detected by EPR.In toluene solution, the major reaction products are tar, the corresponding fluorinated anilines, and azo compounds.
Synthesis and antitumor activity of α,β-unsaturated carbonyl moiety- containing oleanolic acid derivatives targeting PI3K/AKT/mTOR signaling pathway
Wang, Shi-Sheng,Zhang, Qiao-Li,Chu, Peng,Kong, Ling-Qi,Li, Guang-Zhe,Li, Yue-Qing,Yang, Li,Zhao, Wei-Jie,Guo, Xiu-Han,Tang, Ze-Yao
, (2020)
Oleanolic acid (OA) and its semi-synthetic derivatives have been reported to have a wide range of biological activities. The introduction of electrophilic Michael acceptor group can increase the reactivity of OA to cellular targets and thus improve the an
