1233377-01-9Relevant academic research and scientific papers
Electrogenerated base-promoted synthesis of N-benzylic rhodanine and carbamodithioate derivatives
Tissaoui, Khalil,Raouafi, Noureddine,Boujlel, Khaled
, p. 41 - 48 (2010)
Electrogenerated magnesium-associated cyanomethyl anions/bases obtained from the electrochemical reduction of acetonitrile and the oxidation of a sacrificial magnesium rod were successfully used to promote the addition of carbon disulfide to primary benzylic amines. Alkylation with ethyl 3-bromopropionate acid ester or with ethyl 2-bromoacetate acid ester yields the corresponding ring-opened carbamodithioate compounds or cyclic rhodanine derivatives, respectively. The effect of the amount of electrogenerated base on the yield of reaction was also evaluated.
