123363-85-9

Basic information

• Product Name: (4S,5S)-4-Benzyloxymethyl-5-[2-isocyano-2-(toluene-4-sulfonyl)-pentyl]-2,2-dimethyl-[1,3]dioxolane
• CAS NO: 123363-85-9
• Molecular Weight: 471.618
• Mol File: 123363-85-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4S,5S)-4-Benzyloxymethyl-5-[2-isocyano-2-(toluene-4-sulfonyl)-pentyl]-2,2-dimethyl-[1,3]dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5S)-4-Benzyloxymethyl-5-[2-isocyano-2-(toluene-4-sulfonyl)-pentyl]-2,2-dimethyl-[1,3]dioxolane(123363-85-9)
• EPA Substance Registry System: (4S,5S)-4-Benzyloxymethyl-5-[2-isocyano-2-(toluene-4-sulfonyl)-pentyl]-2,2-dimethyl-[1,3]dioxolane(123363-85-9)

Safety Data

• Hazardous Substances Data: 123363-85-9(Hazardous Substances Data)

Upstream product

• 58379-82-1 1-((1-isocyanobutyl)sulfonyl)-4-methylbenzene 
• 114826-50-5 (4R,5S)-2,2-dimethyl-4-iodomethyl-5-benzyloxymethyl-1,3-dioxolane 

Relevant articles and documents

A CONVENIENT REDUCTION OF ALKYLATED TOSYLMETHYL ISOCYANIDES: APPLICATIONS FOR THE SYNTHESIS OF NATURAL PRODUCTS

A convenient and simple method for the reduction of mono- and dialkylated tosylmethyl isocyanides with lithium in liquid ammonia to corresponding hydrocarbons is described.The utility of this methodology adopted in the synthesis of tricos-9Z-ene (7g), a sex pheromone of common house fly, (-)-1S,5R,7S-exo-brevicomin (17), an antipode of sex pheromone of Western pine beetle and (4S,5S)-5-hydroxy-4-decanolide (L-factor, 19), a proposed autoregulator for leukaemomycin biosynthesis.