1233765-57-5Relevant academic research and scientific papers
Cobalt-catalyzed generation of 1,4-dienes as synthons for 1,3-dicarbonyl compounds and their application in natural product syntheses
Hilt, Gerhard,Arndt, Marion,Weske, Damian F.
, p. 1321 - 1324 (2010)
The cobalt-catalyzed 1,4-hydrovinylation of alkenes with 1,3-dienes and the cobalt-catalyzed Diels-Alder reaction of alkynes with 1,3-dienes lead to acyclic and cyclic 1,4-dienes, respectively. These products can be transformed into 1,3-dicarbonyl functional groups by ozonolysis or alternative carbon-carbon double bond cleaving reactions. The application towards the synthesis of hepialone and a pyranone-type lipid from Vanilla beans is described. Georg Thieme Verlag Stuttgart · New York.
