123457-66-9Relevant articles and documents
SCOPE AND LIMITATIONS OF THE ALDOL CONDENSATION CATALYZED BY IMMOBILIZED ACYLNEURAMINATE PYRUVATE LYASE
Auge, Claudine,Bouxom, Benedicte,Cavaye, Bertrand,Gautheron, Christine
, p. 2217 - 2220 (1989)
New substrates have been used in the aldol condensation catalyzed by immobilized acylneuraminate pyruvate lyase: hexoses 3, 4, 7, 8 and pentoses 2, 5, 6.Condensation of pyruvate with 2-5, 7 and 8 led to pure compounds related to 3-deoxy-D-glycero-D-galacto-nonulosonic acid (KDN).Surprisingly, condensation with D-arabinose 6 gave a mixture of diastereomers, 3-deoxy-α-D-manno-2-octulosonic acid (KDO) and 4-epi KDO.