123458-71-9Relevant academic research and scientific papers
REACTION OF SULFUR WITH ORGANIC COMPOUNDS XXVI. REACTIONS OF SULUR WITH TOLUENE AND ITS EXO-SUBSTITUTED DERIVATIVES
Przewocki, K.,Voronkov, M. G.,Przewocka, L.,Varnke, Z.
, p. 2147 - 2154 (2007/10/02)
The reactions of sulfur with toluene and its exo-substituted derivatives of the PhCH2X type, where X = H, Cl, Br, I, OH, OCOMe, COOH, CH2Ph, SH, C(OH)(Ph)CH2Ph, and PhCH=Y, where Y = O, CHPh, C(Ph)CH2Ph, and also with 2-phenylbenzothiophene at 200 deg C and at the autogenous pressure were studied.In all cases the products of these reactions were bibenzyl, E- and Z-stilbenes, 2-phenylbenzothiophene, E- and Z-1,2,3-triphenylpropenes, 1,2,3-triphenylpropane, 2-phenyl-3-benzylbenzothiophene, tetraphenylthiophene, and pentaphenylcyclopentadiene, the ratios of whichare determined by the nature of the substituent X or Y.The high-molecular-weight reaction products with M 240 (34 compounds) were identified.
