1234619-15-8Relevant articles and documents
Preparation and Physicochemical Properties of [6]Helicenes Fluorinated at Terminal Rings
Církva, Vladimír,Jakubík, Pavel,Stra?ák, Tomá?,Hrbá?, Jan,Sykora, Jan,Císa?ová, Ivana,Vacek, Jan,?ádny, Jaroslav,Storch, Jan
, (2019)
The first racemization-stable helicene derivatives fluorinated at terminal rings, 1,2,3,4-tetrafluoro[6]helicene (6) and 1,2,3,4,13,14,15,16-octafluoro[6]helicene (15), were synthesized via the Wittig reaction followed by oxidative photocyclization in an
Homo-elimination of HF - An efficient approach For intramolecular aryl-aryl coupling
Amsharov, Konstantin Yu.,Kabdulov, Mikhail A.,Jansen, Martin
supporting information; experimental part, p. 5868 - 5871 (2010/09/09)
(Figure Presented) A process of elimination: The throughspace fluorine activation in the benzo[c]phenanthrene cyclisation process has been examined experimentally and confirmed theoretically (see figure). Thermally provoked HF homo-elimination was found to be an efficient approach for selective intramolecular aryl-aryl coupling. The data obtained provide new prospects for the synthesis of non-planar aromatic hydrocarbons and fullerenes employing the flash vacuum pyrolysis technique.