1234619-16-9Relevant academic research and scientific papers
Homo-elimination of HF - An efficient approach For intramolecular aryl-aryl coupling
Amsharov, Konstantin Yu.,Kabdulov, Mikhail A.,Jansen, Martin
, p. 5868 - 5871 (2010)
(Figure Presented) A process of elimination: The throughspace fluorine activation in the benzo[c]phenanthrene cyclisation process has been examined experimentally and confirmed theoretically (see figure). Thermally provoked HF homo-elimination was found to be an efficient approach for selective intramolecular aryl-aryl coupling. The data obtained provide new prospects for the synthesis of non-planar aromatic hydrocarbons and fullerenes employing the flash vacuum pyrolysis technique.
