1234714-90-9Relevant academic research and scientific papers
Gold-catalyzed oxidative coupling reactions with aryltrimethylsilanes
Brenzovich Jr., William E.,Brazeau, Jean-Francois,Toste, F. Dean
supporting information; experimental part, p. 4728 - 4731 (2010/12/25)
During continuing studies with a novel oxidative gold oxyarylation reaction, arylsilanes were found to be competent coupling partners, providing further evidence for an intramolecular electrophilic aromatic substitution mechanism. While providing yields complementary to those of the previously described boronic acid methods, the use of trimethylsilanes reduces the observation of homocoupling byproducts and allows for facile intramolecular coupling reactions.
Arylsilanes: Application to gold-catalyzed oxyarylation of alkenes
Ball, Liam T.,Green, Michael,Lloyd-Jones, Guy C.,Russell, Christopher A.
supporting information; experimental part, p. 4724 - 4727 (2010/12/25)
Arylsilanes are efficient reagents for the gold-catalyzed oxyarylation of alkenes (21 examples, up to 85% isolated yield). Using commercially available Ph3PAuCl and readily prepared, benign arylsilanes, these two- and three-component reactions
