123475-42-3Relevant academic research and scientific papers
THE CHEMISTRY OF VICINAL TRICARBONYL COMPOUNDS. APPLICATIONS IN THE SYNTHESIS OF VINCAMINE-RELATED ALKALOIDS
Wasserman, Harry H.,Kuo, Gee-Hong
, p. 873 - 876 (1989)
A vicinal tricarbonyl system attached to a suitable ester residue has been used as a key unit in the synthesis of the indole alkaloids, eburnamonine and tacamonine.
Oxidation of ylide precursors to vicinal tricarbonyls. Applications in vincamine alkaloid synthesis
Wasserman,Kuo
, p. 7071 - 7082 (2007/10/02)
Attachment of carbethoxyalkyl residues to an α,β-diketo ester provides dielectrophilic species applicable to the synthesis of the vincamine alkaloids, eburnamonine and tacamonine. The required vicinal tricarbonyl aggregates were formed by oxidation of suitable ylide precursors with ozone or singlet oxygen.
The Chemistry of Vicinal Tricarbonyl Compounds. Short Synthesis of Eudistomins T, I and M
Wasserman, Harry H.,Kelly, Terence A.
, p. 7117 - 7120 (2007/10/02)
The formation of three novel 1,2,3-tricarbonyl compounds and their use in the total synthesis of eudistomins T, I and M is described.
