1234910-76-9Relevant academic research and scientific papers
Chemo-, regio-, and stereoselective synthesis of syn -aryl glycol monoesters from aryl olefins with hydrogen peroxide catalyzed by RuCl 3
Zhang, Yanqiao,Chu, Guobiao,Cui, Xiaoxue,Han, Zhijie,Dou, Daoke,Chen, Yuanli,Yu, Xiaosong,Li, Chunbao
supporting information; experimental part, p. 1118 - 1122 (2010/06/20)
Chemo-, regio-, and stereoselectivity have been achieved in the oxidations of aryl olefins. The aryl olefins were oxidized by 2 equivalents of H 2O2 in acetic acid, catalyzed by 0.02 equivalent of RuCl3, leading to the formations of syn-aryl glycol monoesters. As the reaction is concerted, both the regio- and stereoselectivity are excellent. In the presence of aliphatic C=C bonds, the aryl C=C bonds were selectively dioxygenated. This represents the first example of chemoselective dioxygenation of aryl C=C bonds. Georg Thieme Verlag Stuttgart - New York.
