123508-03-2Relevant academic research and scientific papers
Intermolecular visible-light photoredox atom-transfer radical [3+2]-cyclization of 2-(iodomethyl)cyclopropane-1,1-dicarboxylate with alkenes and alkynes
Gu, Xiangyong,Li, Xiang,Qu, Yue,Yang, Qi,Li, Pixu,Yao, Yingming
, p. 11878 - 11882 (2013)
Radical chemistry! A visible-light-promoted, tin/boron-free intermolecular [3+2] atom-transfer radical cyclization reaction was developed by using iridium polyphenylpridinyl complex as the sensitizer (see scheme). 2-(Iodomethyl) cyclopropane-1,1-dicarboxylate reacted with various alkenes and alkynes to form cyclopentane and cyclopentene derivatives. Copyright
Atom Transfer Addition and Annulation Reactions of Iodomalonates
Curran, Dennis P.,Chen, Meng-Hsin,Spletzer, Eric,Seong, Churl Min,Chang, Chi-Tai
, p. 8872 - 8878 (2007/10/02)
Atom transfer addition and annulation reactions of iodomalonates with alkyl- and phenyl-substituted alkenes are described.For example, sunlamp irradiation of dimethyl methyliodomalonate and 1-hexene in the presence of 10percent hexabutylditin provides dim
