1235137-06-0

Upstream product

• 545-06-2 trichloroacetonitrile 
• 1071226-24-8 p-tolyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-1-thio-α-D-mannopyranoside 
• 1071226-08-8 p-tolyl 2-O-benzyl-4,6-O-benzylidene-3-O-p-methoxybenzyl-1-thio-α-D-mannopyranoside 
• 824-94-2 p-methoxybenzyl chloride 
• 755002-33-6 para-tolyl (R)-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 218937-72-5 ethyl 2-O-benzyl-4,6-O-benzylidene-3-O-p-methoxybenzyl-1-thio-α-D-mannopyranoside 

Relevant academic research and scientific papers

Influence of remote functional groups towards the formation of 1,2-cis glycosides: Special emphasis on β-mannosylation

A convenient straightforward method has been developed for 1,2-cis glycosylation and β-mannosylation in excellent yields using glycosyl donors having a 4,6-O-benzylidene acetal together with a p-methoxybenzyl (PMB) or 2-naphthylmethyl (NAP) group at the C-3 position under standard glycosylation conditions.

Rate-dependent inverse-addition β-selective mannosylation and contiguous sequential glycosylation involving β-mannosidic bond formation

The β-selectivity of mannosy-lation has been found to be dependent on the addition rate of the mannosyl trichloroacetimidate donor in an inverse-addition (I-A) procedure. This rate dependent I-A procedure can improve the selectivity of direct β-mannosylat