123522-48-5Relevant academic research and scientific papers
DIASTEREOSELECTIVE SYNTHESIS OF BICYCLOOCTANES BY DOUBLE MICHAEL ADDITION
Spitzner, Dietrich,Wagner, Peter,Simon, Arndt,Peters, Karl
, p. 547 - 550 (2007/10/02)
Several chiral acrylates (7b-f) react with kinetically controlled generated lithium dienolate 6a to form chiral bicyclooctanes 4 with modest d.e..It was found, that the diastereoselection is improved, when the corresponding trimethylsilyl ether 6b
