123524-53-8

Basic information

• Product Name: 1,1'-binaphthyl-4,4'-dicarboxylic acid
• CAS NO: 123524-53-8
• Molecular Weight: 342.351
• Mol File: 123524-53-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1'-binaphthyl-4,4'-dicarboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-binaphthyl-4,4'-dicarboxylic acid(123524-53-8)
• EPA Substance Registry System: 1,1'-binaphthyl-4,4'-dicarboxylic acid(123524-53-8)

Safety Data

• Hazardous Substances Data: 123524-53-8(Hazardous Substances Data)

Usage

Structure

Dianionic derivative of binaphthyl, consisting of two naphthyl rings linked by a carbon-carbon bond

Application

Chiral ligand in asymmetric synthesis and catalysis

Effective in promoting

Various asymmetric reactions, such as hydrogenation, isomerization, and cyclopropanation

Interaction

With metal ions

Role in asymmetric transformations

Participation in the process due to its unique structure

Value

Valuable tool in organic synthesis

Upstream product

• 16650-55-8 4-bromonaphthalene-1-carboxylic acid 
• 50672-84-9 4-bromo-1-naphthaldehyde 
• 6627-78-7 1-bromo-4-methylnaphthalene 
• 79996-99-9 1-bromo-4-bromomethyl-naphthalene 
• 481-91-4 4,4'-diamino-1,1'-binaphthyl 
• 115584-22-0 4,4'-Dicyano-1,1'-dinaphthyl 

Relevant articles and documents

UiO-67-type Metal-Organic Frameworks with Enhanced Water Stability and Methane Adsorption Capacity

The structure and properties of two new UiO-67-type metal-organic frameworks, along with their linker synthesis and powder and single crystal synthesis, are presented. The new MOFs, UiO-67-Me and UiO-67-BN, are based on 3,3′-dimethylbiphenyl and 1,1′-binaphthyl linker scaffolds, and show a much higher stability to water than the thoroughly investigated UiO-67, which is based on the biphenyl scaffold. On the basis of structure models obtained from single crystal X-ray diffraction, it is seen that these linkers are partly shielding the Zr cluster. The new materials have higher density than UiO-67, but show a higher volumetric adsorption capacity for methane. UiO-67-BN exhibits excellent reversible water sorption properties, and enhanced stability to aqueous solutions over a wide pH range; it is to the best of our knowledge the most stable Zr-MOF that is isostructural to UiO-67 in aqueous solutions.