50672-84-9Relevant articles and documents
Aggregation-induced emission active D-π-A binaphthyl luminophore with dual-mode fluorescence
Sasaki, Shunsuke,Niko, Yosuke,Igawa, Kazunobu,Konishi, Gen-Ichi
, p. 33474 - 33477 (2014)
A novel aggregation-induced emission active dye consisting of a simple and highly solvatochromic D-π-A type 1,1′-binaphthyl chromophore was synthesised. The new dye exhibited dual-mode fluorescence in response to different types of restriction of intramolecular rotation; aggregation induces green emission, and blue emission is observed in a glassy matrix. the Partner Organisations 2014.
A new 2D Cu-MOF constructed from carboxylate ligands containing C-H?π interactions as a recyclable responsive luminescent sensor for VOCs
Liu, Chengxin,Cui, Jin,Wang, Yufang,Zhang, Mingjie
supporting information, p. 4124 - 4128 (2021/04/06)
A new type of 2D metal-organic framework (MOF), namely Cu-MOF, was constructed from Cu(NO3)2·3H2O and the novel ligand 1,4-bis(4-naphthoic acid)benzene. The C-H?π interactions in the Cu-MOF effectively reduced aggregation-caused quenching (ACQ) due to restrictions in intramolecular motion (RIM), increased fluorescence, and controlled crystal packing properties, resulting in low dimensional parallelogram channels and a responsive “turn-on” fluorescence. The activated Cu-MOF exhibited excellent chemical sensing properties to various volatile organic compounds (VOCs) and showed excellent recyclability.
Synthesis of 2,6-dimethoxy-9-phenyl-1H-phenalen-1-one and structural revision of the benzoindenone from Eichhornia crassipes
Li, Xiaowan,Si, Tongxu,Ku, Chuenfai,Zhang, Hongjie,Wang, Mingzhong,Chan, Albert S.C.
, p. 183 - 189 (2019/01/21)
The total synthesis of the natural phytoalexin 2,6-dimethoxy-9-phenyl-1H-phenalen-1-one (3) isolated from Eichhornia crassipes was accomplished in seven steps. The synthetic strategy included a Friedel-Crafts acylation and a Jacobsen-Katsuki epoxidation as the key reactions to obtain the target compound. Based on a comparison of the NMR data and a crystal structure of 3, the previously proposed structure of 2,5-dimethoxy-4-phenyl-benzoindenone (2) isolated from the same plant has been revised.