123534-01-0

Basic information

• Product Name: 3-Pyridinamine, 6-methoxy-N-(phenylmethylene)-
• CAS NO: 123534-01-0
• Molecular Formula: C13H12N2O
• Molecular Weight: 212.251
• Mol File: 123534-01-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Pyridinamine, 6-methoxy-N-(phenylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pyridinamine, 6-methoxy-N-(phenylmethylene)-(123534-01-0)
• EPA Substance Registry System: 3-Pyridinamine, 6-methoxy-N-(phenylmethylene)-(123534-01-0)

Safety Data

• Hazardous Substances Data: 123534-01-0(Hazardous Substances Data)

Upstream product

• 6628-77-9 6-methoxy-pyridin-3-ylamine 
• 100-52-7 benzaldehyde 

Downstream Products

• 4114-28-7 diethyl hydrazodicarboxylate 
• 138409-81-1 6-methoxy-2,4-diphenyl-1,5-naphthyridine 
• 138409-82-2 6-methoxy-2,4-diphenyl-1,7-naphthyridine 

Relevant articles and documents

Annulation Reactions with Iron(III) Chloride: Oxidation of Imines

Aromatic imines react with phenylacetylene or styrene in an acetonitrile solution of iron(III) chloride to give quinolines 3 or their tetrahydro derivatives 11 together with variable amounts of products 4 arising from the reduction of the imines.The initial step appears to be a one-electron oxidation to generate iron(II) and an imine radical cation.When the reactions are carried out in the presence of stoichiometric amounts of tetrachloro-p-benzoquinone (chloranil), only quinolines 3 are obtained.