123536-65-2

Upstream product

• 68295-80-7 (1S,5S)-5-Hydroxy-cyclohex-3-enecarboxylic acid methyl ester 
• 1166841-87-7 acetic acid (S)-5-oxo-cyclohex-3-enylmethyl ester 
• 79644-03-4 (1S,5S)-6-oxabicyclo<3.2.1>oct-3-en-7-one 
• 5708-19-0 (1S)-3-cyclohexenecarboxylic acid 
• 155703-00-7 Acetic acid (S)-3-methoxymethoxy-5-oxo-cyclohex-3-enylmethyl ester 
• 155702-97-9 5-Hydroxymethyl-3-methoxymethoxy-cyclohex-2-enone 
• 19373-86-5 (+/-)-5-hydroxymethyl-3-methoxycyclohexenone 
• 155751-19-2 (R)-5-Hydroxymethyl-3-methoxymethoxy-cyclohex-2-enone 
• 123453-95-2 (1S,5S)-(-)-5-(hydroxymethyl)-2-cyclohexen-1-ol 
• 123536-66-3 (1S,4S,5S)-4-iodo-6-oxabicyclo<3.2.1>octan-7-one 

Downstream Products

• 70552-71-5 (5S)-5-<(1-ethoxyethoxy)methyl>-2-cyclohexen-1-one 
• 132436-32-9 (4S,5E,7S,9R,10R)-9,10-epoxy-4-isopropyl-7-<(o-nitrophenyl)selenomethyl>-5-cyclodecen-1-one 
• 70552-73-7 (5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one 
• 70552-73-7 (5S,6R)-5-(1-Ethoxy-ethoxymethyl)-6-((E)-3-methyl-but-1-enyl)-cyclohex-2-enone 
• 84162-00-5 (1S,5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-1-vinyl-2-cyclohexen-1-ol 
• 123453-96-3 (5S,6S)-5-(1-Ethoxy-ethoxymethyl)-6-((1S,2R)-1-hydroxy-3-methyl-2-phenylselanyl-butyl)-cyclohex-2-enone 
• 123453-96-3 (5S,6S,1'R^*,2'R)-5-<(1-ethoxyethoxy)methyl>-6-(1'-hydroxy-3'-methyl-2'-phenylselenobutyl)-2-cyclohexen-1-one 
• 61228-92-0 (3S,8R,9R,10S)-(-)-periplanone-B 
• 1256355-94-8 (S)-5-(4-methoxybenzyloxymethyl)cyclohex-2-enone 

Relevant academic research and scientific papers

Synthesis and Evaluation of Oligomeric Thioether-Linked Carbacyclic β-(1?3)-Glucan Mimetics

Extrapolating from lessons learnt with previous low-molecular-weight β-(1?3)-glucan mimetics, we designed a series of minimal 2,4-dideoxy-thioether-linked carbacyclic β-(1?3)-glucan mimetics and synthesized di-, tri-, and tetramers in an enantiomerically

Asymmetric synthesis of palitantin by an enzymatic and organocatalytic approach

The natural enantiomer of the fungal metabolite (+)-palitantin has been synthesized by adopting a chemoenzymatic and organocatalytic approach. Lipase catalyzed kinetic resolution, Sharpless asymmetric dihydroxylation and organocatalytic asymmetric hydroxy

Chemo-enzymatic asymmetric total synthesis of penienone

An asymmetric synthesis of penienone has been accomplished from (R)-5-hydroxymethyl-2-cyclohexenone by adopting a linear strategy. Lipase-PS-catalyzed enzymatic kinetic resolution (EKR) and Julia-Kocienski olefination followed by substrate-directed anioni

Efficient synthesis of optically active cyclohexenones

Optically active 5-hydroxymethylcyclohexenones and 5- acetoxymethylcyclohexenones were efficiently obtained by enzymatic enantioselective esterification and chemical conversion.

Synthesis of (-)-periplanone-B, a sex pheromone component of the American cockroach (Periplaneta americana)

The naturally occurring (-)-enantiomer of periplanone-B was synthesized stereoselectively starting from (S)-3-cyclohexene-1-carboxylic acid. The crystalline pheromone was obtained in 12% overall yield through 18 steps.

A new stereoselective synthesis of (-)-periplanone-B

Optically pure (-)-periplanone-B, a sex pheromone component of the American cockroach (Periplaneta americana), was synthesized from (S)-3-cyclohexene-1-carboxylic acid in 18 steps. About 300 mg of the crystalline pheromone was obtained in 11% overall yield.