70552-73-7

Upstream product

• 84782-52-5 3-methyl-2-(phenylseleno)butyraldehyde 
• 70552-71-5 (5S)-5-<(1-ethoxyethoxy)methyl>-2-cyclohexen-1-one 
• 5708-19-0 (1S)-3-cyclohexenecarboxylic acid 
• 123536-66-3 (1S,4S,5S)-4-iodo-6-oxabicyclo<3.2.1>octan-7-one 
• 123536-65-2 (5S)-5-hydroxymethyl-2-cyclohexen-1-one 
• 123453-95-2 (1S,5S)-(-)-5-(hydroxymethyl)-2-cyclohexen-1-ol 
• 79644-03-4 (1S,5S)-6-oxabicyclo<3.2.1>oct-3-en-7-one 
• 590-86-3 isovaleraldehyde 
• 123453-96-3 (5S,6S)-5-(1-Ethoxy-ethoxymethyl)-6-((1S,2R)-1-hydroxy-3-methyl-2-phenylselanyl-butyl)-cyclohex-2-enone 
• 123453-96-3 (5S,6S,1'R^*,2'R)-5-<(1-ethoxyethoxy)methyl>-6-(1'-hydroxy-3'-methyl-2'-phenylselenobutyl)-2-cyclohexen-1-one 
• 123453-96-3 (5S,6S,1'RS,2'RS)-5-<(1-ethoxyethoxy)methyl>-6-(1'-hydroxy-3'-methyl-2'-phenylselenobutyl)-2-cyclohexen-1-one 

Downstream Products

• 61228-92-0 (3S,8R,9R,10S)-(-)-periplanone-B 
• 132436-32-9 (4S,5E,7S,9R,10R)-9,10-epoxy-4-isopropyl-7-<(o-nitrophenyl)selenomethyl>-5-cyclodecen-1-one 
• 132436-31-8 (2Z,6E)-(5S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-8-isopropyl-5-(2-nitro-phenylselanylmethyl)-cyclodeca-2,6-dienone 
• 84162-00-5 (1S,5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-1-vinyl-2-cyclohexen-1-ol 
• 84162-00-5 (1S,5S,6R,1'E)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-1-vinyl-2-cyclohexen-1-ol 

Relevant academic research and scientific papers

Synthesis of (-)-periplanone-B, a sex pheromone component of the American cockroach (Periplaneta americana)

The naturally occurring (-)-enantiomer of periplanone-B was synthesized stereoselectively starting from (S)-3-cyclohexene-1-carboxylic acid. The crystalline pheromone was obtained in 12% overall yield through 18 steps.

SYNTHESIS OF BOTH THE ENANTIOMERS OF HAUPTMANN'S PERIPLANONE-A AND CLARIFICATION OF THE STRUCTURE OF PERSOON'S PERIPLANONE-A

The naturally occuring (-)-enantiomer of Hauptmann's periplanone-A and its stereoisomers were synthesized.Thermal rearrangement of Hauptmann's (-)-periplanone A by GLC gave Persoon's periplanone-A, the structure of which was determined through an X-ray cr