123541-65-1Relevant academic research and scientific papers
Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst
Arico, Caterina S.,Cox, Liam R.
, p. 2558 - 2562 (2004)
Grubbs' first-generation, Ru metathesis complex 3 catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.
Ru-Catalyzed Migratory Geminal Semihydrogenation of Internal Alkynes to Terminal Olefins
Song, Lijuan,Feng, Qiang,Wang, Yong,Ding, Shengtao,Wu, Yun-Dong,Zhang, Xinhao,Chung, Lung Wa,Sun, Jianwei
, p. 17441 - 17451 (2019/11/03)
Semihydrogenation of alkynes to alkenes represents a fundamentally useful transformation. In addition to the well-known cis- and trans-semihydrogenation, herein a geminal semihydrogenation of internal alkynes featuring 1,2-migration is described, which pr
Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes
Andavan, Gurusamy Thangavelu Senthil,Bauer, Eike B.,Letko, Christopher S.,Hollis, T. Keith,Tham, Fook S.
, p. 5938 - 5947 (2007/10/03)
1,3-Bis(3-butylimidazolium-1-yl)benzene diiodide (1) was reacted with Li(2,2,6,6-tetramethylpiperidine) yielding the free bis-carbene, 1,3-bis(3-butylimidazol-2-ylidene-1-yl)benzene (3), which has been spectroscopically characterized. Combining the free b
Manganese-Catalyzed Silylmagnesiation of Acetylenes and 1,3-Dienes
Tang, Jun,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 245 - 251 (2007/10/03)
The treatment of 4-benzyloxy-1-butyne with PhMe2SiMgMe in the presence of a catalytic amount of MnCl2 gave a monosilylated product, (E)-PhCH2OCH2CH2CH=CHSiMe2Ph, selectively after an aqueou
A 1,2-Silicon Shift in Cyclopropylidenes leading to 1-Trialkylsilylcyclopropenes
Baird, Mark S.,Dale, Cynthia M.,Dulayymi, Juma'a R. Al
, p. 1373 - 1374 (2007/10/02)
1,1-Dibromo-2-trialkylsilylcyclopropanes, readily prepared by dibromocyclopropanation of vinyltrialkylsilanes, react with methyllithium at -90 to 20 deg C to give high yields of trialkylsilylcyclopropenes in which the silicon has apparently migrated to C-1.
