123568-06-9Relevant academic research and scientific papers
α-Silyl Sulfones as Latent α-Sulfonyl Anions. Fluoride-Promoted Intramolecular 1,2-Additions to Aldehydes as the Basis of a New Cyclopentenylation Strategy
Anderson, M. B.,Fuchs, P. L.
, p. 337 - 342 (2007/10/02)
Conjugate Addition of allylpotassium to vinyl sulfones 8 and 23 followed by carbon silylation provides α-silyl sulfones 9d and 24b.These materials are transformed to aldehydes 11 and 26, which subsequently undergo smooth fluoride-induced cyclopentannulati
