123568-08-1

Upstream product

• 123568-07-0 3-((3aS,4S,5R,7R,7aR)-5-Benzenesulfonyl-2,2,3a,7-tetramethyl-5-trimethylsilanyl-hexahydro-benzo[1,3]dioxol-4-yl)-propionaldehyde 
• 123568-06-9 3-((3aS,4S,5R,7R,7aR)-5-Benzenesulfonyl-2,2,3a,7-tetramethyl-5-trimethylsilanyl-hexahydro-benzo[1,3]dioxol-4-yl)-propan-1-ol 
• 123568-14-9 ((3aS,4S,5R,7R,7aR)-4-Allyl-5-benzenesulfonyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-5-yl)-trimethyl-silane 
• 82769-83-3 cis-3,4-dihydroxy-trans-3,5-dimethyl-1-(phenylsulfonyl)cyclohexene 3,4-acetonide 

Relevant academic research and scientific papers

α-Silyl Sulfones as Latent α-Sulfonyl Anions. Fluoride-Promoted Intramolecular 1,2-Additions to Aldehydes as the Basis of a New Cyclopentenylation Strategy

Conjugate Addition of allylpotassium to vinyl sulfones 8 and 23 followed by carbon silylation provides α-silyl sulfones 9d and 24b.These materials are transformed to aldehydes 11 and 26, which subsequently undergo smooth fluoride-induced cyclopentannulati