1235835-84-3Relevant academic research and scientific papers
Synthesis and characterization of dendrimeric bridged salen/saloph complexes and investigation of their magnetic and thermal behaviors
Koc, Ziya Erdem,Uysal, Saban
, p. 910 - 919 (2010)
Eight new multinuclear FeIII and CrIII complexes involving the tetradentate Schiff bases N,N′-bis(salicylidene) ethylenediamine (salenH2) or N,N′-bis(salicylidene)benzene-1,2- diamine (salophH2) and the two new ligands 4,4′,4″, 4?,4′?,4″?-[1,3,5-triazine-2,4, 6-triyltris(nitrilomethylidyne-4,1-phenyleneoxy-1,3,5-triazine-6,2, 4-triyldiimino)]hexakis[benzoic acid] (4) or 5,5′,5″,5?, 5′?,5″?-[1,3,5-triazine-2,4,6- triyltris(nitrilomethylidyne-4,1-phenyleneoxy-1,3,5-triazine-6,2,4-triyldiimino) ]hexakis[benzene-1,3-dicarboxylic acid] (5) were synthesized (Schemes 1 and 2) and characterized by means of 1H-NMR and FT-IR spectroscopy, elemental analysis, LC/MS analysis, AAS (atomic-absorption spectrum) analysis, thermal analyses, and magnetic-susceptibility measurements. The complexes can also be characterized as low-spin distorted-octahedral FeIII and CrIII complexes bridged by carboxylato moieties.
