123597-18-2Relevant academic research and scientific papers
Catalytic Cyclophanes. 4. Supramolecular Catalysis of Benzoin Condensations by a Thiazolium Cyclophane
Diederich, Francois,Lutter, Heinz-Dieter
, p. 8438 - 8446 (1989)
As a model for thiamine pyrophosphate dependent ligases, the thiazolium-bridged cyclophane 1 was prepared in a 14-step synthesis.Compound 1 was designed to catalyze the benzoin condensation, and its macrocyclic cavity provides in aqueous and organic solut
