Catalytic Cyclophanes. 4. Supramolecular Catalysis of Benzoin Condensations by a Thiazolium Cyclophane

DOI: 10.1021/ja00204a017

Source and publish data:

Journal of the American Chemical Society p. 8438 - 8446 (1989)

Update date:2022-08-05

Topics: Supramolecular Catalysis Benzoin condensation

Authors:

Diederich, Francois

Lutter, Heinz-Dieter

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Article abstract of DOI:10.1021/ja00204a017

As a model for thiamine pyrophosphate dependent ligases, the thiazolium-bridged cyclophane 1 was prepared in a 14-step synthesis.Compound 1 was designed to catalyze the benzoin condensation, and its macrocyclic cavity provides in aqueous and organic solut

Full text of DOI:10.1021/ja00204a017

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