Journal of the American Chemical Society p. 8438 - 8446 (1989)
Update date:2022-08-05
Diederich, Francois
Lutter, Heinz-Dieter
As a model for thiamine pyrophosphate dependent ligases, the thiazolium-bridged cyclophane 1 was prepared in a 14-step synthesis.Compound 1 was designed to catalyze the benzoin condensation, and its macrocyclic cavity provides in aqueous and organic solut
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