1236046-56-2Relevant academic research and scientific papers
Acylation of Arenes with Aldehydes through Dual C-H Activations by Merging Photocatalysis and Palladium Catalysis
Wang, Haiyang,Li, Tao,Hu, Dongyan,Tong, Xiaogang,Zheng, Liyan,Xia, Chengfeng
, p. 3772 - 3776 (2021)
An acylation of arenes with aldehydes through dual C-H activations at room temperature is reported. The acylation was initiated by phenanthraquinone-catalyzed hydrogen atom transfer from aldehyde under visible light irradiation. The aldehyde-derived acyl
Manganese-Catalyzed Direct Nucleophilic C(sp2)-H Addition to Aldehydes and Nitriles
Zhou, Bingwei,Hu, Yuanyuan,Wang, Congyang
supporting information, p. 13659 - 13663 (2015/11/16)
Herein, a manganese-catalyzed nucleophilic addition of inert C(sp2)-H bonds to aldehydes and nitriles is disclosed by virtue of a dual activation strategy. The reactions feature mild reaction conditions, excellent regio- and stereoselectivity, and a wide substrate scope, which includes both aromatic and olefinic C-H bonds, as well as a large variety of aldehydes and nitriles. Moreover, mechanistic studies shed light on possible catalytic cycles.
Decarboxylative acylation of arenes with α-oxocarboxylic acids via palladium-catalyzed C-H activation
Li, Mingzong,Ge, Haibo
supporting information; experimental part, p. 3464 - 3467 (2010/10/01)
(Equation Presented). An efficient palladium-catalyzed decarboxylative acylation of unactivated arenes with α-oxocarboxylic acids is reported. This method provides a novel access to aryl ketones.
