1236074-59-1

Basic information

• Product Name: 3-(4-chloro-phenyl)-2-phenylsulfanylmethyl-acrylic acid methyl ester
• Synonyms: 3-(4-chloro-phenyl)-2-phenylsulfanylmethyl-acrylic acid methyl ester
• CAS NO: 1236074-59-1
• Molecular Weight: 318.824
• Mol File: 1236074-59-1.mol

Chemical Properties

• CAS DataBase Reference: 3-(4-chloro-phenyl)-2-phenylsulfanylmethyl-acrylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-chloro-phenyl)-2-phenylsulfanylmethyl-acrylic acid methyl ester(1236074-59-1)
• EPA Substance Registry System: 3-(4-chloro-phenyl)-2-phenylsulfanylmethyl-acrylic acid methyl ester(1236074-59-1)

Safety Data

• Hazardous Substances Data: 1236074-59-1(Hazardous Substances Data)

Upstream product

• 131469-72-2 methyl 3-acetoxy-3-(4-chlorophenyl)-2-methylenepropanoate 
• 882-33-7 diphenyldisulfane 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 139413-75-5 methyl (2Z)-2-(bromomethyl)-3-(4-chlorophenyl)prop-2-enoate 

Relevant articles and documents

Metal-free, regio- and stereoselective S-methylation/phenylation of allyl halides using sulfoxides as sulfenylating agent

A DCP promoted metal-free, regio and stereoselective S-methylation/phenylation of allyl halides using sulfoxides as sulfenylating agent is described. A variety of multifunctional allyl halides underwent S-methylation and S-phenylation by using dimethyl sulfoxide (DMSO) and diphenyl sulfoxide (DPSO) under the reaction conditions employed to provide the resulting thioethers in good to excellent yields.

Regio- and stereoselective syntheses of allylic thioethers under metal free conditions

A metal free, regio and stereoselective syntheses of allylic thioethers using allyl iodides and aryl or alkyl disulfides as coupling partners is described. The densely functionalized allyl iodides having different stereochemistry (E & Z) reacted well with a variety of disulfides in a regio and stereoselective manner providing the resulting allyl aryl thioethers in 62-92% yields.

Stereoselective cross-coupling of baylis-hillman acetates with diphenyl disulfides and diselenides using palladium acetate

An efficient method is described for the stereoselective synthesis of diorganyl chalcogenides from a variety of Baylis-Hillman acetates and diaryl chalcogens using palladium catalyst. This reaction is a convenient new method to produce unsymmetrical sulfides and selenides in good yields. Copyright Taylor & Francis Group, LLC.