123614-01-7Relevant academic research and scientific papers
Stereoselective synthesis of (Z)-1-Silyl-2-stannylethene by palladium-catalyzed silastannation of ethyne and its synthetic transformations
Murakami, Masahiro,Matsuda, Takanori,Itami, Kenichiro,Ashida, Shinji,Terayama, Miki
, p. 1522 - 1526 (2007/10/03)
(Z)-1-Silyl-2-stannylethenes were stereoselectively synthesized by silastannation of ethyne, catalyzed by a palladium/tert-alkyl isocyanide catalyst, and the synthetic utilities were demonstrated by their transformations.
PALLADIUM CATALYZED COUPLING OF ORGANOSTANNANES WITH VINYL EPOXIDES
Tueting, David R.,Echavarren, Antonio M.,Stille, J. K.
, p. 979 - 992 (2007/10/02)
The coupling reaction of organotin reagents with vinyl epoxides, catalyzed by palladium, takes place at ambient temperatures, regioselectively, giving predominately the 1,4-addition product.Both aryl- and vinylstannanes undergo coupling in high yields, wh
