1236155-99-9Relevant academic research and scientific papers
A 1,3-carbonyl shift in the platinum-catalyzed aromatization of 2-epoxy-1-(methoxyalk-2-ynyl)benzenes
Chaudhuri, Rupsha,Das, Arindam,Liao, Hsin-Yi,Liu, Rai-Shung
, p. 4601 - 4603 (2010)
A platinum-catalyzed reaction involving new aromatization/1,3-carbonyl shift cascade of 2-epoxy-1-(methoxyalk-2-ynyl)benzenes is reported. This skeletal rearrangement is mechanistically significant because it involves a remarkable 1,3-carbonyl shift to complete the aromatization and to regenerate the catalyst.
