123629-12-9

Basic information

• Product Name: ((Z)-1-Ethyl-propenyloxy)-methyl-diphenyl-silane
• CAS NO: 123629-12-9
• Molecular Weight: 282.458
• Mol File: 123629-12-9.mol

Chemical Properties

• CAS DataBase Reference: ((Z)-1-Ethyl-propenyloxy)-methyl-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z)-1-Ethyl-propenyloxy)-methyl-diphenyl-silane(123629-12-9)
• EPA Substance Registry System: ((Z)-1-Ethyl-propenyloxy)-methyl-diphenyl-silane(123629-12-9)

Safety Data

• Hazardous Substances Data: 123629-12-9(Hazardous Substances Data)

Upstream product

• 123629-10-7 2-(Methyl-diphenyl-silanyl)-pentan-3-one 

Relevant articles and documents

A REGIO- AND STEREOSELECTIVE SYNTHESIS OF (Z) ENOL METHYLDIPHENYLSILYL ETHERS

The thermal rearrangement of α-(methyldiphenylsilyl) ketones in an apolar solvent or in the absence of a solvent provides Z:E mixtures of the corresponding enol silyl ethers.This same rearrangement in acetonitrile, however, gives the Z isomer cleanly, thus providing a regio- and stereoselective entry into (Z) enol silyl ethers.