Tetrahedron Letters p. 283 - 286 (1989)
Update date:2022-08-04
Topics:
Larson, Gerald L.
Berrios, Reyes
Prieto, Jose A.
The thermal rearrangement of α-(methyldiphenylsilyl) ketones in an apolar solvent or in the absence of a solvent provides Z:E mixtures of the corresponding enol silyl ethers.This same rearrangement in acetonitrile, however, gives the Z isomer cleanly, thus providing a regio- and stereoselective entry into (Z) enol silyl ethers.
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