123629-14-1Relevant articles and documents
A REGIO- AND STEREOSELECTIVE SYNTHESIS OF (Z) ENOL METHYLDIPHENYLSILYL ETHERS
Larson, Gerald L.,Berrios, Reyes,Prieto, Jose A.
, p. 283 - 286 (2007/10/02)
The thermal rearrangement of α-(methyldiphenylsilyl) ketones in an apolar solvent or in the absence of a solvent provides Z:E mixtures of the corresponding enol silyl ethers.This same rearrangement in acetonitrile, however, gives the Z isomer cleanly, thus providing a regio- and stereoselective entry into (Z) enol silyl ethers.