91413-20-6

Basic information

• Product Name: 1-Decanone, 2-(methyldiphenylsilyl)-1-phenyl-
• CAS NO: 91413-20-6
• Molecular Formula: C29H36OSi
• Molecular Weight: 428.69
• Mol File: 91413-20-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Decanone, 2-(methyldiphenylsilyl)-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Decanone, 2-(methyldiphenylsilyl)-1-phenyl-(91413-20-6)
• EPA Substance Registry System: 1-Decanone, 2-(methyldiphenylsilyl)-1-phenyl-(91413-20-6)

Safety Data

• Hazardous Substances Data: 91413-20-6(Hazardous Substances Data)

Upstream product

• 89638-16-4 ethyl 2-(diphenylmethylsilyl)decanoate 

Downstream Products

• 123629-14-1 Methyl-diphenyl-((Z)-1-phenyl-dec-1-enyloxy)-silane 

Relevant articles and documents

Reaction of α-Silyl Esters with Grignard Reagents: A Synthesis of β-Keto Silanes and Ketones. Preparation of the Douglas Fir Tussock Moth Pheromone

A variety of α-diphenylmethylsilyl esters have been prepared and reacted with Grignard reagents.The reaction is relatively slow in refluxing THF and can be controlled to allow the addition of 1 equiv of the Grignard reagent, providing the corresponding β-keto silane.Protiodesilylation of the β-keto silane results in the overall conversion of an ester to a ketone.This ester to ketone methodology has been applied to a two-step synthesis of the pheromone of the Douglas fir tussock moth.The β-keto silanes are viable precursors to regioselectively generated enol silyl ethers.The reaction of ethyl 2-methyl-2-(diphenylmethylsilyl)propionate with vinylmagnesium bromide or 2-methyl 1-propenylmagnesium bromide results in the addition of 2 equiv of the Grignard reagent, the second in a Michael fashion.