1236291-77-2Relevant academic research and scientific papers
Synthesis and properties of pentacoordinated phenoxysilane and carboxysilanes with intramolecular nitrogen-silicon coordination
Domoto, Yuya,Saruhashi, Kowichiro,Fukushima, Akihiro,Sase, Shohei,Goto, Kei,Kawashima, Takayuki
, p. 1221 - 1229 (2010)
Reactions of a neutral pentacoordinated monohydrosilane bearing a dative N-Si bond with phenol and benzoic acid derivatives gave the corresponding pentacoordinated phenoxysilane and carboxysilanes, respectively. X-ray crystallographic analyses of these silanes revealed that the distance of the N-Si dative bond is shortened and the pentacoordination character of the silicon center becomes greater with the increase in the electron-withdrawing character of the apical substituent on silicon. Copyright Taylor & Francis Group.
