123630-52-4

Basic information

• Product Name: (E)-4-acetoxy-5-phenylthio-oct-4-ene
• Synonyms: (E)-4-acetoxy-5-phenylthio-oct-4-ene
• CAS NO: 123630-52-4
• Molecular Weight: 278.415
• Mol File: 123630-52-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-4-acetoxy-5-phenylthio-oct-4-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-acetoxy-5-phenylthio-oct-4-ene(123630-52-4)
• EPA Substance Registry System: (E)-4-acetoxy-5-phenylthio-oct-4-ene(123630-52-4)

Safety Data

• Hazardous Substances Data: 123630-52-4(Hazardous Substances Data)

Upstream product

• 1942-45-6 4-Octyne 
• 882-33-7 diphenyldisulfane 
• 10534-59-5 tetrabutylammonium acetate 
• 64168-52-1 4'-nitrobenzenesulfenanilide 
• 64-19-7 acetic acid 

Downstream Products

• 39601-01-9 5-(phenylthio)octan-4-one 

Relevant articles and documents

Generation and reactions of thiirenium ions by the Cation Pool method

Thiirenium ions generated and accumulated by low-temperature electrochemical oxidation of disulfides in the presence of alkynes were successfully observed by low-temperature NMR, Raman, and mass spectroscopies and were found to be stable at temperatures below -40 °C. The thiirenium ions showed ambident reactivity toward subsequently added nucleophiles to give either disubstituted alkenes or alkynes depending on the nature of the nucleophiles.