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123673-03-0

Methyl (2R,4S)-2-(p-Nitrophenoxy)-2-oxo-3-benzyl-1,3,2-oxazaphospholidine-4-carboxylate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 123673-03-0 Structure

  • Basic information

    1. Product Name: Methyl (2R,4S)-2-(p-Nitrophenoxy)-2-oxo-3-benzyl-1,3,2-oxazaphospholidine-4-carboxylate
    2. Synonyms:
    3. CAS NO:123673-03-0
    4. Molecular Formula:
    5. Molecular Weight: 392.305
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 123673-03-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Methyl (2R,4S)-2-(p-Nitrophenoxy)-2-oxo-3-benzyl-1,3,2-oxazaphospholidine-4-carboxylate(CAS DataBase Reference)
    10. NIST Chemistry Reference: Methyl (2R,4S)-2-(p-Nitrophenoxy)-2-oxo-3-benzyl-1,3,2-oxazaphospholidine-4-carboxylate(123673-03-0)
    11. EPA Substance Registry System: Methyl (2R,4S)-2-(p-Nitrophenoxy)-2-oxo-3-benzyl-1,3,2-oxazaphospholidine-4-carboxylate(123673-03-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 123673-03-0(Hazardous Substances Data)

123673-03-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 123673-03-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,3,6,7 and 3 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 123673-03:
(8*1)+(7*2)+(6*3)+(5*6)+(4*7)+(3*3)+(2*0)+(1*3)=110
110 % 10 = 0
So 123673-03-0 is a valid CAS Registry Number.

123673-03-0Downstream Products

123673-03-0Relevant articles and documents

Synthesis, Configuration, and Chemical Shift Correlations of Chiral 1,3,2-Oxazaphospholidin-2-ones Derived from l-Serine

Thompson,Charles M.,Frick, Jeffrey A.,Green, Diana L.C.

, p. 111 - 116 (1990)

The reaction between (S)-methyl N-benzylserinoate and phosphorous oxychloride leads to the diastereomeric chloro-1,3,2-oxazaphospholidin-2-ones.Reaction of the chloridates with alcohols or phenols in the presence of base affords the corresponding alkoxy (or aryloxy) derivatives (66-94percent), which were readily separated by standard chromatographic methods.The stereochemical arrangement of these compounds was established by NMR chemical shift correlations (carbon-13 and phosphorus-31) and single-crystal X-ray analysis.The trans geometry of the carbomethoxy and exocyclicphosphorus ligand resulted in approximately a 1 ppm upfield shift in the phosphorus-31 spectra relative to the cis isomer.The carbon-13 NMR spectra revealed an opposite trend to the heteroatom-bound alkyl region with most of the trans isomer signals appearing downfield (0.2-1.2 ppm) from the corresponding cis isomer.

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