1236879-87-0Relevant academic research and scientific papers
Gold-catalyzed tandem cyclization of dienol silyl ethers for the preparation of bicyclo[4.3.0]nonane derivatives
Kusama, Hiroyuki,Karibe, Yusuke,Onizawa, Yuji,Iwasawa, Nobuharu
, p. 4269 - 4272 (2010)
[Figure Presented] Tandem bicycle: A gold-catalyzed geminal carbo-functionalization reaction of 3-siloxy-1,3-dien-8-ynes proceeded smoothly to give bicyclo[4.3.0]nonanes stereoselectively through ring expansion of the bicyclic carbene complex intermediates. The product configuration was different from that of the thermal Diels-Alder adduct.
